過去の論文


2004年度 2003年度 2002年度
2001年度 2000年度 1999年度

2004年度

13

小島直人

抗腫瘍活性バンレイシ科アセトゲニン類の系統的不斉合成法の開発
Yakugaku Zasshi, 124, 673-681 (2004).

12

N. Maezaki, H. Sawamoto, T. Suzuki, R. Yoshigami, and T. Tanaka

Highly Stereoselective Synthesis of Functionalized β, β-Di- and Trisubstituted Vinylic Sulfoxides by Cu-Catalyzed Conjugate Addition of Organozinc Reagents
J. Org. Chem. 69, 8387-8393 (2004).

11

N. Maezaki, H. Sawamoto, S. Yuyama, R. Yoshigami, T. Suzuki, M. Izumi, H. Ohishi, and T. Tanaka

Asymmetric Intramolecular Michael Addition of α-Sulfinyl Vinylic Carbanion to Enoates
J. Org. Chem. 69, 6335-6340 (2004).

10

K. Hayashi, S. M. A. Rahman, H. Ohno, T. Tanaka, N. Toyooka, H. Nemoto, and T. Hayashi

Evaluation of Scopadulciol-Related Molecules for Their Stimulatory Effect on the Cytotoxicity of Acyclovir and Ganciclovir against Herpes Simplex Virus Type 1 Thymidine Kinase Gene-Transfected HeLa Cells
Chem. Pharm. Bull. 52, 1015-1017 (2004).

9

H. Ohno, H. Iwasaki, T. Eguchi, and T. Tanaka

The First Samarium(II)-Mediated Aryl Radical Cyclization onto an Aromatic Ring
Chem. Commun. 2228-2229 (2004).

8

N. Maezaki, Y. Hirose, and T. Tanaka

Stereoselective Synthesis of 1,4-Bifunctional Compounds by Regioselective Pd-Catalyzed Allylic Substitution Reaction
Org. Lett. 6, 2177-2180 (2004).

7

H. Ohno, Y. Takeoka, Y. Kadoh, K. Miyamura, and T. Tanaka

Palladium(0)-Catalyzed Stereoselective Cyclization of Allenenes: Synthesis of Pyrrolidines and 3-Azabicyclo[3.1.0]hexanes from Single Allenenes
J. Org. Chem. 69, 4541-4544 (2004).

6

H. Ohno, H. Hamaguchi, M. Ohata, S. Kosaka, and T. Tanaka

Palladium(0)-Catalyzed Synthesis of Medium-Sized Heterocycles by Using Bromoallenes as an Allyl Dication Equivalent
J. Am. Chem. Soc. 126, 8744-8754 (2004).

5

N. Kojima, N. Maezaki, H. Tominaga, M. Yanai, D. Urabe, and T. Tanaka

Stereodeivergent and Reiterative Synthesis of Bis-tetrahydrofuran Ring Cores in Annonaceous Acetogenins
Chemistry - A European Journal 10, 672-680 (2004).

4

N. Maezaki, S. Yagi, J. Maeda, R. Yoshigami, and T. Tanaka

Geometrically Selective Synthesis of Sulfur-containing Heterocycles by Intramolecular Pd-catalyzed Sulfinylzincation
Heterocycles 62, 263-277 (2004).

3

N. Maezaki, H. Tominaga, N. Kojima, M. Yanai, D. Urabe, and T. Tanaka

First total synthesis of murisolin
Chem. Commun. 406-407 (2004).

2

H. Ohno, Y. Takemoto, N. Fujii, T. Tanaka, T. Ibuka

Stereodivergent Synthesis of Chiral 2-Alkenylaziridines: Palladium(0)-Catalyzed 2,3-cis-Selective Aziridination and Base-Mediated 2,3-trans-Selective Aziridination
Chem. Pharm. Bull. 52, 111-119 (2004).

1

H. Ohno, K. Hiramatsu, T. Tanaka

Asymmetric Construction of Quaternary Carbon Centers by Allyltitanium-Mediated Stereospecific Ring-Opening Reaction of 2,3-Epoxy Alcohols
Tetrahedron Lett. 45, 75-78 (2004).
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2003年度

14

H. Ohno, Y. Takeoka, K. Miyamura, Y. Kadoh, and T. Tanaka

Novel Synthesis of 3-Azabicyclo[3.1.0]hexanes by Unusual Palladium(0)-Catalyzed Cyclopropanation of Allenenes
Org. Lett., 5, 4763-4766 (2003).

13

N. Maezaki, S. Yagi, S. Ohsawa, H. Ohishi, and T. Tanaka

Synthesis of chiral vinylic sulfoxides by Pd-catalyzed asymmetric sulfinylzincation
Tetrahedron, 59, 9895-9906 (2003).

12

N. Kojima, N. Maezaki, H. Tominaga, M. Asai, M. Yanai, and T. Tanaka

Systematic Construction of a Monotetrahydrofuran-Ring Library in Annonaceous Acetogenins by Asymmetric Alkynylation and Stereodivergent Tetrahydrofuran-Ring Formation
Chemistry - A European Journal, 9, 4980-4990 (2003).

11

H. Ohno, H. Hamaguchi, M. Ohata, S. Kosaka, T. Tanaka

Novel Synthesis of Azocine, Azepine, Oxocine, and Oxepine Derivatives by Palladium-Catalyzed Medium-Ring Fomation from Bromoallenes
Heterocycles, 61, 65-68 (2003).

10

H. Ohno, M. Okumura, S. Maeda, H. Iwasaki, R. Wakayama, T. Tanaka

Samarium(II)-Promoted Radical Spirocyclization onto an Aromatic Ring
J. Org. Chem. 68, 7722-7732 (2003).

9

H. Ohno, R. Wakayama, S. Maeda, H. Iwasaki, M. Okumura, C. Iwata,
H.Mikamiyama, T. Tanaka

Radical Cyclization by ipso Substitution of Methoxy Group: Considerable Effect of HMPA on Samarium-Mediated Cyclization
J. Org. Chem., 68, 5909-5916 (2003).

8

N. Maezaki, S. Yagi, R. Yoshigami, J. Maeda, T. Suzuki, S. Ohsawa,
K. Tsukamoto, and T. Tanaka

Pd-Catalyzed Sulfinylzincation of Activated Alkynes with 1-Alkynyl Sulfoxides as a Sulfinyl Source
J. Org. Chem., 68, 5550-5558 (2003).

7

N. Maezaki, H. Sawamoto, R. Yoshigami, T. Suzuki, and T. Tanaka

Geometrically Selective Synthesis of Functionalized β,β-Disubstituted Vinylic Sulfoxides by Cu-Catalyzed Conjugate Addition of Organozinc Reagents to 1-Alkynyl Sulfoxides
Org. Lett., 5, 1345-1347 (2003).

6

N. Maezaki, N. Kojima, H. Tominaga, M. Yanai, and T. Tanaka

Systematic Synthesis of bis-THF Ring Cores in Annonaceous Acetogenins
Org. Lett., 5, 1411-1414 (2003).

5

H. Ohno, K. Miyamura, Y. Takeoka, T. Tanaka

First Palladium(0)-Catalyzed Tandem Cyclization of Allenenes
Angew. Chem. Int. Ed., 42, 2647-2650 (2003);
Angew. Chem., 115, 2751-2754 (2003).

4

H. Ohno, H. Hamaguchi, M. Ohata, T. Tanaka

Bromoallenes as Synthetic Equivalents of Allyl Dications: Synthesis of Medium-Sized Nitrogen Heterocycles through the Cyclization of Bromoallenes in the Presence of a Palladium(0) Catalyst and an Alcohol
Angew. Chem. Int. Ed., 42, 1749-1753 (2003);
Angew. Chem., 115, 1791-1795 (2003).

3 

M. Yamashita, N. Ohta, T. Shimizu, K. Matsumoto, Y. Matsuura, I. Kawasaki, T. Tanaka, N. Maezaki, and S. Ohta
The First Total Synthesis of (±)-Linderol A, a Tricyclic
Hexahydrodibenzofuran Constituent of Lindera Umbellata Bark, with Potent Inhibitory Activity on Melanin Biosynthesis of Cultured B-16 Melanoma Cells
J. Org. Chem., 68, 1216-1224 (2003).

2

N. Maezaki, N. Kojima, A. Sakamoto, H. Tominaga, C. Iwata, T. Tanaka, M. Monden, B. Damdinsuren, and S. Nakamori.

Total Synthesis of Mosin B, an Antitumor Acetogenin: Desymmetrization Approach to Stereodivergent Synthesis of threo/trans/erythro-Type Acetogenins
Chemistry - A European Journal, 9, 389-399 (2003).

1

N. Maezaki, A. Furusawa, S. Uchida, T. Tanaka

3-CYANO-2-(N-CYANOIMINO)THIAZOLIDINE (3-CYANO-NCT): AN EFFICIENT ELECTROPHILIC CYANATING AGENT FOR ACTIVATED METHYLENE COMPOUNDS

Heterocycles, 59, 161-167 (2003).
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2002年度

8

M. Anzai, R. Yanada, N. Fujii, H. Ohno, T. Ibuka, Y. Takemoto
Asymmetric Synthesis of b2,3-Amino Acids by InI-Pd(0)-promoted Metalation and Addition of Chiral 2- Vinylaziridines
Tetrahedron, 58 , 5231-5239 (2002).

7

H. Ohno, K. Ando, H. Hamaguchi, Y. Takeoka, T. Tanaka
A Highly cis-Selective Synthesis of 2-Ethynylaziridines by
Intramolecular Amination of Chiral Bromoallenes: Improvement of Stereoselectivity Based on the Computational Investigation
J. Am. Chem. Soc., 124, 15255-15266 (2002).

6

N. Maezaki, S. Yagi, S. Ohsawa, H. Ohishi, and T. Tanaka
Pd-Catalyzed Asymmetric Sulfinylzincation of 1-Alkynoates
Using 1-Alkynyl Sulfoxides Bearing a Chiral Auxiliary

Tetrahedron: Asymmetry, 13 , 1961-1964 (2002).

5

前崎 直容、田中 徹明

スルフィニル基の特性を利用した新規合成反応の開発と天然物合成への応用

生産と技術, 54, 46-49 (2002).

4

N. Maezaki, N. Kojima, M. Asai, H. Tominaga, and T. Tanaka

Highly Stereoselective and Stereodivergent Synthesis of Four Types of THF Cores in Acetogenins Using a C4-Chiral Building Block

Org. Lett., 4, 2977-2980 (2002).

3

N. Maezaki, A. Furusawa, Y. Hirose, S. Uchida, T. Tanaka

3-Phosphono-2-(N-cyanoimino)thiazolidine derivatives, new
phosphorylating agents for alcohols

Tetrahedron, 58, 3493-3498 (2002).

2

H. Ohno, S. Maeda, M. Okumura, R. Wakayama, and T. Tanaka

The First Samarium(II)-Mediated Stereoselective Spirocyclization onto an Aromatic Ring

Chem. Commun., 316-317 (2002).

1

H. Ohno, K. Miyamura, T. Tanaka, S. Oishi, A. Toda, Y. Takemoto, N. Fujii, and T. Ibuka

Synthesis of Allenes from Allylic Alcohol Derivatives Bearing a Bromine Atom Using a Palladium(0)/Diethylzinc System

J. Org. Chem., 67, 1359-1369 (2002).

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2001年度

16

H. Ohno

Development of Aziridination and Azetizination Reactions of Amino Allenes Using Palladium Catalyst

Yakugaku Zasshi, 121, 733-741 (2001)

15

N. Maezaki, R. Yoshigami, J. Maeda, and T. Tanaka

Palladium-Catalyzed Sulfinylzincation: 1-Alkynyl Sulfoxides as a Sulfinyl Anion Equivalent

Org. Lett., 3, 3627-3629 (2001)

14

N. Maezaki, A. Furusawa, S. Uchida and T. Tanaka

3-Acyl-2-(N-cyanoimino)oxazolidine derivative, a new asymmetric acylating agent for racemic secondary alkyl amines

Tetrahedron, 57, 9309-9315 (2001)

13

T. Tanaka, K. Murakami, A. Kanda, D. Patra, S. Yamamoto, N. Satoh, S.-W. Kim, S. M. A. Rahman, H. Ohno, and C. Iwata

Total Synthesis of (±)-Stemodinone via an Efficient Ring-Exchange Strategy

J. Org. Chem., 66, 7107-7112 (2001)

12

S. M. A. Rahman, H. Ohno, and T. Tanaka

Improved Method of an Unusual Conversion of Aliphatic Amines into Alcohols

Tetrahedron Lett., 428007-8010 (2001)

11

Y. Takemoto, K. Ishii, T, Ibuka, Y, Miwa, T, Taga, S, Nakao, T, Tanaka, H, Ohishi, Y, Kai, and N, Kanehira

Stereospecific 1,3-Migration of an Fe(CO)3 Group on Acyclic Conjugated Polyenes: Application to Remote and Iterative Asymmetric Induction

J. Org. Chem., 66, 6116-6123 (2001)

10

H. Ohno, H. Hamaguchi, and T. Tanaka

Stereoselective Synthesis of Chiral 2,3-cis-2-Ethynylaziridines by Base-Mediated Intramolecular Amination of Bromoallenes

Org. Lett., 3, 2269-2271 (2001)

9

H. Ohno, M. Anzai, A. Toda, S. Ohishi, N. Fujii, T. Tanaka, Y. Takemoto, and T. Ibuka

Stereoselective Synthesis of 2-Alkenylaziridines and 2-Alkenylazetidines by Palladium-Catalyzed Intramolecular Amination of a- and b-Amino Allenes

J. Org. Chem., 66, 4904-4914 (2001)

8

S. M. A. Rahman, H. Ohno, T. Murata, H. Yoshino, N. Satoh, K. Murakami, D. Patra, C. Iwata, N. Maezaki, and T. Tanaka

Total Synthesis of (±)-Scopadulin

J. Org. Chem., 66, 4831-4840 (2001)

7

H. Ohno, H. Hamaguchi, and T. Tanaka

2-Ethynylaziridines as Chiral Carbon Nucleophiles: Stereoselective Synthesis of 1,3-Amino Alcohols with Three Stereocenters via Allenylindium Reagents Bearing a Protected Amino Group

J. Org. Chem., 66, 1867-1875 (2001)

6

Y. Takemoto, M. Anzai, R. Yanada, N. Fujii, H. Ohno, and T. Ibuka

Stereoselective Synthesis of Nonracemic 1,3-Amino Alcohols from Chiral 2-Vinylaziridines by InI-Pd(0)-Promoted Metalation

Tetrahedron Lett., 42, 1725-1728 (2001)

5

Y. Baba, G. Saha, S. Nakao, C. Iwata, T. Tanaka, T. Ibuka, H. Ohishi, and Y. Takemoto

Asymmetric Total Synthesis of Halicholactone

J. Org. Chem., 66, 81-88 (2001)

4

S. M. A. Rahman, H. Ohno, T. Murata, H. Yoshino, N. Satoh, K. Murakami, D. Patra, C. Iwata, N. Maezaki, and T. Tanaka

The First Total Synthesis of (±)-Scopadulin, an Antiviral Aphidicolane Diterpene

Org. Lett., 3, 619-621 (2001)

3

N. Maezaki, N. Kojima, A. Sakamoto, C. Iwata, and T. Tanaka

First Total Synthesis of Mosin B

Org. Lett., 3, 429-432 (2001)

2

N. Maezaki, S. Yuyama, H. Sawamoto, T. Suzuki, M. Izumi, and T. Tanaka

Highly Stereoselective Intramolecular Michael Addition Using a-Sulfinyl Vinyllithium as an Unprecedented Michael Donor

Org. Lett., 3, 29-31 (2001)

1

S. M. A. Rahman, H. Ohno, H. Yoshino, N. Satoh, M. Tsukaguchi, K. Murakami, C. Iwata, N. Maezaki, and T. Tanaka

A Successful Model Study for the Total Synthesis of (±)-Scopadulin: Stereoselective Construction of A/B Ring System with Desired Functionalities

Tetrahedron, 57, 127-134 (2001)

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2000年度

13

S. M. A. Rahman, H. Ohno, N. Maezaki, C. Iwata and T. Tanaka

Efficient One-Step Conversion of Primary Aliphatic Amines into Primary Alcohols: Application to a Model Study for the Total Synthesis of (±)-Scopadulin

Org. Lett., 2, 2893-2895 (2000)

12

H. Ohno, H. Hamaguchi, and T. Tanaka

Umpolung of Chiral 2-Ethynylaziridines: Indium(I)-Mediated Stereoselective Synthesis of Nonracemic 1,3-Amino Alcohols Bearing Three Chiral Centers, Catalyzed by Palladium(0)

Org. Lett., 2, 2161-2163 (2000)

11

N. Maezaki, M. Izumi, S. Yuyama, H. Sawamoto, C. Iwata, and T. Tanaka

Studies on Intramolecular Alkylation of an a-Sulfinyl Vinylic Carbanion: A Novel Route to Chiral 1-Cycloalkenyl Sulfoxides 

Tetrahedron, 56, 7927-7945 (2000).

10

K. Ando, T. Oishi, M. Hirama, H. Ohno, and T. Ibuka

Z-Selective Horner-Wadsworth-Emmons Reaction of Ethyl(Diarylphosphono)acetates Using Sodium Iodide and DBU

J. Org. Chem, 65, 4745-4749 (2000)

9

N. Maezaki, Y.-X. Li, K. Ohkubo, S. Goda, C. Iwata, and T. Tanaka

Asymmetric Desymmetrization of a s-Symmetric Erythritol Derivative Using C2-Symmetric Bis-sulfoxide: A Total Synthesis of (+)-Aspicilin

Tetrahedron, 56, 4405-4413 (2000)

8

H. Ohno, A. Toda, T. Tanaka, S. Oishi, Y. Takemoto, N. Fujii, and T. Ibuka

Novel Synthesis of Chiral Terminal Allenes via Palladium(0)-Catalyzed Reduction of Mesylates of 2-Bromoalk-2-en-1-ols Bearing a Protected Amino Group, Using Diethylzinc

Tetrahedron Lett., 41, 5131-5134 (2000)

7

N. Maezaki, A. Sakamoto, N. Nagahashi, M. Soejima, Y. -X. Li, T. Imamura, N. Kojima, H. Ohishi, K. Sakaguchi, C. Iwata, and T. Tanaka

C2-Symmetric Bis-Sulfoxide: A Novel Chiral Auxiliary for Asymmetric Desymmetrization of Cyclic meso-1,2-Diols

J. Org. Chem., 65, 3284-3291 (2000)

6

Y. Takemoto, Y. Baba, G. Saha, S. Nakao, C. Iwata, T. Tanaka, and T. Ibuka

Asymmetric Total Synthesis of Halicholactone

Tetrahedron Lett., 41, 3653-3656 (2000) 

5

T. Tanaka, R. Wakayama, S. Maeda, H. Mikamiyama, N. Maezaki and H. Ohno

Unusual Radical ipso-Substitution Reaction of an Aromatic Methoxy Group Induced by Tris(trimethylsilyl)silane-AIBN or SmI2

Chem. Commun., 1287-1288 (2000)

4

H. Ohno, A. Toda, N. Fujii, Y. Takemoto, T. Tanaka, and T. Ibuka

Stereoselective Synthesis of Chiral Amino Allenes by Organocopper-mediated Anti SN2'-substitution Reaction of Chiral Ethynylaziridines

Tetrahedron, 56, 2811-2820 (2000)

3

T. Tanaka, X. Fang, T. Azuma, S. Uchida, T. Ishida, Y. In, C. Iwata, and N. Maezaki

3-Acyl-4-diphenylmethyl-2-(N-cyanoimino)thiazolidine: An Enantioselective Acylation Reagent for Racemic Amines

J. Chin. Chem. Soc., 47, 865-868 (2000)

2

T. Tanaka, T. Azuma, X. Fang, S. Uchida, C. Iwata, T. Ishida, Y. In, and N. Maezaki

A New Sulfenylation Reagent, 3-Phenylsulfenyl-2-(N-cyanoimino)thiazolidine, and Its Optically Active Version

Synlett, 32-36 (2000)

1

Y. Takemoto, K. Ishii, Y. Miwa, T. Taga, T. Ibuka, S. Nakao, and T. Tanaka

Stereospecific 1,3-Migration of an Fe(CO)3 Group on Acyclic Conjugated Trienes Bearing an Electron-withdrawing Group

Tetrahedron Lett., 41, 85-88 (2000)

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1999年度

5

Y. Takemoto, N. Yoshikawa, Y. Baba, C. Iwata, T. Tanaka, T. Ibuka, and H. Ohishi

Utility of a Diene-Tricarbonylion complex as a Mobile Chiral Auxiliary: Regio- and Stereocontrolled Functionalization of Acyclic Diene Ligands

J. Am. Chem. Soc., 121, 9143-9154 (1999)

4

Y. Takemoto, S. Huruse, H. Hayase, T. Echigo, C. Iwata, T. Tanaka, and T. Ibuka

CAN-Induced Double Ether-Ring Formation: Synthesis of Trans- and Cis-Fused Tricyclic Ethers from 3-Oxabicyclo[3.1.0]hexyl Sulfides

Chem. Commun., 2515-2516 (1999)

3

N. Maezaki, N. Nagahashi, R. Yoshigami, C. Iwata, and T. Tanaka

Synthetic Research on Cyclitols Using C6-Chiron, 6-(Benzyloxy)-3-cyclohexen-1-ol: A Concise and Highly Diastereoselective Synthesis of (-)-gala-Quercitol

Tetrahedron Lett., 40, 3781-3784 (1999)

2

N. Maezaki, M. Izumi, S. Yuyama, C. Iwata, and T. Tanaka

Intramolecular Alkylation of an a-Sulfinyl Vinylic Carbanion without Loss of Optical Purity: A Novel Access to Chiral Cyclic Vinylic Sulfoxides

Chem. Commun., 1825-1826 (1999)

1

Y. Li, N. Maeazaki, T. Tanaka, and C. Iwata

Application of a C2-Symmetric Chiral Auxiliary of Bis-Sulfoxide: Asymmetric Desymmetrization of s-Symmetric 1,2-Diol of Ten Membered Oxygen Ring

Journal of Ocean University of Qingdao, 29, 447-452 (1999)

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